By default root user account is disabled for login in Ubuntu. Steps mentioned below will allow you to enable the root user and login as root on the OS.
Login to your account and open Terminal
sudo passwd root
Type in the new password for UNIX
sudo gedit /usr/share/lightdm/lightdm.conf.d/50-unity-greeter.conf
At the end of the file append greeter-show-manual–login = true
That’s all, now reboot the system and you can login to root account using manual login.